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четверг, 5 апреля 2018 г.

Titanium carbide flakes obtained by selective etching of…


Titanium carbide flakes obtained by selective etching of titanium silicon carbide



Metallic conductivity and hydrophilicity of MXenes have established them as electrodes in rechargeable batteries and supercapacitors, as well as other applications, including photothermal cancer therapy, electromagnetic shielding, water purification and gas sensing. In the journal Angewandte Chemie, researchers have now introduced a new production method. Instead of using conventional, yet more expensive, titanium aluminum carbide, they selectively etch silicon out of titanium silicon carbide, a cheaper and more common precursor, to synthesize titanium carbide.


Two-dimensional materials, consisting of extremely thin layers that are a few atoms thick, have unique properties that are completely different than the normal three-dimensional versions. A prominent example of this is graphene, which is made of single layers of carbon atoms. In 2011, a new class of two-dimensional materials was synthesized at Drexel University in Philadelphia (Pennsylvania, USA). Known as MXenes, the materials are made of transition metal carbides and nitrides, where the M stands for a transition metal, such as titanium, vanadium, or molybdenum, X can be carbon and/or nitrogen, and many compositions are available (about 30 have already been experimentally demonstrated and dozens more are expected). One such MXene is titanium carbide, Ti3C2.



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